Bibliographic Metadata
Bibliographic Metadata
- TitleMechanistic Insights into Statistical Co-Assembly of Metal Complexes
- Translated titleMechanistische Einblicke in die statistische Co-Assemblierung von Metallkomplexen
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- AnnotationThis work was supported by the the Humboldt Foundation (Sofja-Kovalevskaja Award) and the European Commission (ERC-StG-2016 SUPRACOP-715923).
- LanguageEnglish
- Bibl. ReferenceChem. Eur. J. (2019) 25, 8960-8964
- Document typeJournal Article
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Abstract
Statistical copolymerization plays a key role in many biological and technological processes; however, mechanistic understanding of the formation of analogous supramolecular counterparts remains limited. Herein, we report detailed insights into the supramolecular co-assembly of two p-conjugated PdII and PtII complexes, which in isolation self-assemble into flexible fibers and nanodisks, respectively. An efficient single-step co-assembly into only one type of nanostructure (fibers or nanodisks) takes place if any of the components is in excess. In contrast, equimolar mixtures lead to PdII-rich fiber-like co-assemblies by a statistical co-nucleation event along with a residual amount of self-sorted nanodisks in a stepwise manner.
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