Kalsani, Venkateshwarlu: Multi-component metallo-supramolecular assemblies. 2005
Inhalt
- Table of Contents
- I Introduction
- II State of Knowledge
- III The HETPHEN Approach
- III-1 The HETPHEN Approach: Interplay of π-π Interactions, Solvent Association, and Steric Hindrance
- III-2 Towards a Kinetically Stable Bisphenanthroline Copper Complex
- IV Synthesis, Structures and Surface Patterning of Bisphenanthrolines. Versatile Precursors For Heteroleptic/Heterometallic Supramolecular Rack and Grids
- IV-1 Synthesis of Soluble, linear BisPhenanthrolines For the construction of Heteroleptic Nanogrids and Nanoboxes
- IV-2 Rigid Bisphenanthrolines: Their Synthesis, Structure and Self-Assembly at the Solid-Liquid Interface and in Solution
- IV-3 Supramolecular Copper Phenanthroline Racks: Structures, Mechanistic Insight and Dynamic Nature
- IV-4 Self-Assembly of Heteroleptic [2x2] and [2x3] Nanogrids
- IV-5 Metal-Driven and Covalent Fabrication of Supramolecular Grids from Racks: A Convergent Approach to Heterometallic and Heteroleptic Nanostructures
- V Multicomponent Aggregates of a Rigid Exotopic Bisphenanthroline Macrocycle and their Characterization in Solution and at Surfaces
- V-1 Synthesis and Self-Assembly of a Rigid Exotopic Bisphenanthroline Macrocycle: Surface Patterning and a Supramolecular Nanobasket
- V-2 Quantitative Formation and Clean Metal Exchange Processes of Large Void (~5000 Å3) Nanobox Structures
- V-3 Heteroleptic Bisphenanthroline Metallo-Nanoscaffolds – A Model Case for the Solution State Charaterisation of Supramolecular Nano Edifices
- V-4 Simple and Supramolecular Copper Complexes as Precursors in the HRTEM Induced Formation of Crystalline Copper Nanoparticles
- VI The HETTAP Approach
- VI-1 The HETTAP Approach: Self-Assembly and Metal Ion Sensing of Dumbbell-Shaped Molecules and A Clip Molecule
- VI-2 A Facile Approach to Dynamic and Fluorescent Nanoscale Phenanthroline/Terpyridine Zinc(II) Ladders
- VI-3 Zn(II)/Ag(I) Nanoscale 2D Ladders Containing Pyrene Units
- VI-4 A Functional Nanoscale Ladder Containing Ferrocene Units
- VII Crystal Structure Data
- VIII Summary
- IX Resume