Titelaufnahme
Titelaufnahme
- TitelChirale Bishydroxylamine: Synthese und Koordinationsverhalten in Silicium- und d(0)-Übergangsmetall-Komplexen
- Verfasser
- Gutachter
- Erschienen
- SpracheDeutsch
- DokumenttypDissertation
- URN
Zugriffsbeschränkung
- Das Dokument ist frei verfügbar
Links
- Social MediaShare
- NachweisKein Nachweis verfügbar
- IIIF
Dateien
Klassifikation
Abstract
New bishydroxylamines with rigid and chiral cyclohexane backbones were synthesized and characterized. These dialkylhydroxylamines could successfully be employed as anionic ligands to complex transition metal ions. The various coordination motifs of the resulting hydroxylaminato complexes were analyzed and the chemistry of bishydroxylamines and their complexes extended by a class of chiral compounds.
In the first part of this work a suitable route for the synthesis of 1,2 cyclohexanediyl-bishydroxylamines was established. This was achieved by a de novo synthesis from cyclohexanediamine. In the second part the research focused on the behavior of cyclohexanediyl bishydroxylamines in complexes with Lewis-acidic metal ions.
Statistik
- Das PDF-Dokument wurde 3 mal heruntergeladen.