Richter, Antje; Floris, Andrea; Bechstein, Ralf; Kantorovich, Lev; Kühnle, Angelika: On-Surface Synthesis on a Bulk Insulator Surface. In: Journal of Physics: Condensed Matter. Jg.30 H. 13. 2018, S. 133001 ff.
Inhalt
- Abstract
- 1. Introduction
- 2. Materials and methods
- 2.1. Calcite (10.4) and organic precursors
- 2.2. Experimental methods: dynamic atomic force microscopy and sample preparation
- 2.3. Theoretical method: density-functional theory calculations
- 3. Molecule–surface interactions: how to anchor the precursor?
- 4. Proof-of-principle: demonstration of aryl–halide coupling on calcite (10.4)
- 4.1. Dimerization
- 4.2. Extended row formation
- 4.3. Detailed reaction mechanism: why does it work in the absence of metals?
- 4.4. Towards hierarchical reactions using step-wise C–C coupling
- 5. Exploring further on-surface reactions
- 5.1. Photochemical [2 + 2] cycloaddition of C60 on calcite (10.4)
- 5.2. Diacetylene polymerization
- 5.3. Coupling of terminal alkynes
- 6. Conclusions and outlook
- Acknowledgments
- ORCID iDs
- References