Höhn, Sebastian: Interaction of Pluronic polymers with sugar surfactant in microemulsions designed for decontamination. 2016
Inhalt
- 1 Prelude
- 2 Introduction
- 2.1 Motivation and structure
- 2.2 Chemical warfare agents
- 2.3 Decontamination
- 2.3.1 Decontaminants I - Solvent
- 2.3.2 Decontaminants II - Active reagent
- 2.3.3 The ideal decontaminant
- 2.4 References
- 3 Theoretical background
- 3.1 Sugar surfactants
- 3.2 Microemulsions
- 3.3 Microemulsion additives
- 3.4 Polymer-surfactant interaction
- 3.5 Microstructure
- 3.6 Theory of microemulsion formation
- 3.7 Scattering techniques
- 3.7.1 Photon correlation spectroscopy
- 3.7.2 Small angle X-ray and neutron scattering
- 3.7.3 Neutron spin echo
- 3.8 References
- 4 Experimental section
- 4.1 Used chemicals
- 4.2 Sample preparation
- 4.3 Phase behaviour
- 4.4 PCS experiments
- 4.5 SAXS experiments
- 4.6 SANS experiments
- 4.7 NSE experiments
- 4.8 References
- 5 Technical system
- 5.1 Lanol 99 - System
- 5.2 Phase behaviour
- 5.2.1 Pluronic polymers
- 5.2.2 Effect of the polymer fraction
- 5.2.3 Variation of PEO/PPO ratio
- 5.2.4 Comparison of the results for all three series
- 5.3 Influence on the internal structure
- 5.4 Microemulsion dynamics
- 5.5 Conclusion
- 5.6 References
- 6 C10G2 system
- 6.1 Phase behaviour
- 6.2 Influence on the micro structure
- 6.2.1 Variation of the polymer content I - X-point
- 6.2.2 Variation of the polymer content II - Constant composition
- 6.2.3 Series 3, Variation of the polymer size
- 6.2.4 Bending elastic constant
- 6.3 Influence on the membrane dynamics
- 6.4 Conclusion
- 6.5 References
- 7 Skin Decontamination
- 7.1 System variation I: Non-polar phase
- 7.2 System variation II: Co-surfactant
- 7.3 Ethyl ester systems.
- 7.4 Conclusion
- 7.5 References
- 8 Summary and future perspectives
- List of Figures
- List of Tables
- Abbreviations
- Danksagung
- Erklärung zur Dissertation