Waske, Prashant Ankushrao: Radical cation cyclization of cyclopropyl silyl ethers induced by PET : synthetic applications for the construction of polycyclic compounds, and Photoacylation [...]. 2006
Inhalt
- Introduction
- Objectives
- Introduction to the Electron Transfer (ET)
- Rates of electron transfer and quantum efficiency of photoin
- Sensitizers and co-sensitizers
- Generation of radical anions via photoinduced electron trans
- Generation of radical cations via photoinduced electron tran
- Generation of radical cations via oxidative PET of olefins
- Generation of radical cation from cyclopropyl silyl ether vi
- Generation of radical cations using cyclopropyl amines via P
- Results and Discussion
- Photoacylation of Quinones
- Results and Discussion
- Summary
- Experimental
- General Procedure A: Synthesis of silyl enol ethers with CuI
- General procedure B: Synthesis of silyl enol ether by LDA
- General procedure C: Cyclopropanation of silyl enol ethers
- General procedure D: PET oxidative reaction
- General Procedure E: Synthesis of 3-substituted enones by re
- Synthesis of 3-benzyl-1-trimethylsilyloxylcyclopent-1-ene (5
- Synthesis of 3-benzyl-1-trimethylsilyloxylcyclohex-1-ene (57
- Synthesis of 3-benzyl-1-trimethylsilyloxylcyclohept-1-ene (5
- Synthesis of 3-propargyl-1-trimethylsililoxylcyclohex-1-ene
- Synthesis of 3-(but-3-enyl)-1-trimethylsilyloxylcyclohex-1-e
- Synthesis of 3-(2-phenylethyl)-1-trimethylsilyloxylcyclohex-
- Synthesis of 6-benzyl-1-trimethylsilyloxyl-1,6-cycloheptadie
- Synthesis of 3-methyl-3-(3-methylbut-3-enyl)-1-trimethylsily
- Synthesis of 3-(3-methylbut-3-enyl)-1-trimethylsilyloxylcycl
- Synthesis of 4-benzyl-1-trimethylsilyloxylbicyclo[3.1.0]hexa
- Synthesis of 4-benzyl-1-trimethylsilyloxylbicyclo[4.1.0]hept
- Synthesis of 4-benzyl-1-trimethylsilyloxylbicyclo[5.1.0]octa
- Synthesis of 4-(prop-2-ynyl)-1-trimethylsilyloxylbicyclo[4.1
- Synthesis of 4-(but-3-enyl)-1-trimethylsilyloxylbicyclo[4.1.
- Synthesis of 4-(2-phenylethyl)-1-trimethylsilyloxylcyclohex-
- Synthesis of 3-benzyl-1-trimethylsilyloxylbicyclo[5.1.0]oct-
- Synthesis of 4-(3-methylbut-3-enyl)-1-trimethylsilyloxylbicy
- Synthesis of 3-benzyl-2-cycloheptene-1-one (72)
- Cis-3,4,4a,9,9a,10-Hexahydro-1(2H)-anthracenone (81)
- (5aR,10aS)-5,5a,7,8,9,10,10a,11-Octahydro-6H-cyclohepta[b]na
- 4-Benzylcyclohexanone (83) and 4-benzyl-2-cyclohexen-1-one
- 2-Methyl-3-(2-phenylethyl)-cyclohexanone (85)
- (3S,3aR,8aS)-3-Methyloctahydroazulen-5(1H)-one (86)
- (3aS,8aS)-3,3-Dimethyloctahydroazulen-5(1H)-one (87)
- 3a-Benzyl-hexahydropentalen-2-one (88)
- 3,4,4a,5,8,8a-Hexahydro-1-(2H)-naphthalenone (90)
- General Procedure F: Irradiation of Quinones with Aldehydes
- Photoacylation of 1,4-Naphthoquinones with Aliphatic Aldehyd
- 1-(1,4-Dihydroxy-naphthalen-2-yl)-butan-1-one (106a)29a
- 1-(1,4-Dihydroxy-naphthalen-2-yl)-dodecan-1-one (106b)
- 1-(1,4-Dihydroxy-naphthalen-2-yl)-2-methyl-propan-1-one (106
- 1-(1,4-Dihydroxy-naphthalen-2-yl)-propenone (107) and acryli
- Photoacylation of 1,4-Naphthoquinones with Aromatic Aldehyde
- 4-[(1,4-Dihydroxy-2-naphthyl)carbonyl]benzonitrile (110a)
- (1,4-Dihydroxy-naphthalen-2-yl)-(4-methoxyphenyl)-methanone
- (1,4-Dihydroxy-naphthalen-2-yl)-p-tolyl-methanone (112a) and
- (4-Chloro-phenyl)-(1,4-dihydroxy-naphthanlen-2-yl)-methanone
- (1,4-Dihydroxy-naphthalen-2-yl)-phenyl-methanone (112c) and
- Photoacylation of Methyl Juglone with Aliphatic Aldehydes
- 1-(1,4-Dihydroxy-5-methoxy-naphthalen-2-yl)-2-methyl-propan-
- 1-(1,4-Dihydroxy-5-methoxy-naphthalen-2-yl)-propenone or 1-(
- Photoacylation of Methyl Juglone with Aromatic Aldehydes
- (1,4-Dihydroxy-5-methoxy-naphthalen-2-yl)-phenyl-methanone a
- (1,4-Dihydroxy-5-methoxy-naphthalen-2-yl)-(4-methoxy-phenyl)
- (1,4-Dihydroxy-5-methoxy-naphthalen-2-yl)-p-tolyl-methanone
- 4-[(1,4-Dihydroxy-8-methoxy-2-naphthyl)carbonyl]benzonitrile
- (4-Chloro-phenyl)-(1,4-dihydroxy-5-methoxy-naphthanlen-2-yl)
- Photoacylation Reactions of 2-Methoxy-1,4-Naphthoquinone
- 1-(1,4-Dihydroxy-3-methoxy-naphthalen-2-yl)-butan-1-one (126
- 2-Dodecanoyl-3-methoxy-1,4-naphthoquinone (128)
- Photoacylation Reactions of 2-Methyl-1,4-Naphthoquinone
- 2-Isobutyryl-3-methyl-1,4-naphthoquinone (131a)
- 2-Dodecanoyl-3-methyl-1,4-naphthoquinone (131b)
- 2-Benzoyl-3-methyl-1,4-naphthoquinone (131c)
- 2-(4-Methoxy-benzoyl)-3-methyl-1,4-naphthoquinone (131d)
- 2-(4-Methyl-benzoyl)-3-methyl-1,4-naphthoquinone (131e)
- 2-Butyryl-3-methyl-1,4-naphthoquinone (132) and 2-butyryl-2-
- X-Ray Analysis
- 4-(1,4-Dihydroxy-8-methoxy-naphthalene-2-carbonyl)-benzonitr
- [3-(4-Chloro-phenyl)-1,4-dihydroxy-8-methoxy-naphthalen-2-yl
- 4-Chloro-benzoic acid 4-hydroxy-8-methoxy-naphthalen-1-yl es
- References and notes